The chromatographic behavior of twelve neutral, mixed cobalt(III) complexes of the uns-cis-edda-type has been investigated in six planar chromatographic systems. Four different stationary phases unmodified silica gel, CN-silica, cellulose, and alumina - were combined with water-organic solvent (methanol or acetone) binary mobile phases. The effect of the water content of the mobile phases on retention of the complexes was investigation systematically. On the basis of the results obtained, possible separation mechanisms were considered. Hydrophilic-interaction chromatography was assumed to be the mechanism determining separation tinder normal-phase conditions, i.e. use of mobile phases containing small amounts of water. Reversed-phase chromatography occurs when water-rich mobile phases are used.
TY - JOUR
AU - Radoičić, Aleksandra
AU - Majstorović, Helena
AU - Sabo, Tibor
AU - Tešić, Živoslav
AU - Milojković-Opsenica, Dušanka
PY - 2009
UR - https://intam.institut-tamis.rs/handle/123456789/140
AB - The chromatographic behavior of twelve neutral, mixed cobalt(III) complexes of the uns-cis-edda-type has been investigated in six planar chromatographic systems. Four different stationary phases unmodified silica gel, CN-silica, cellulose, and alumina - were combined with water-organic solvent (methanol or acetone) binary mobile phases. The effect of the water content of the mobile phases on retention of the complexes was investigation systematically. On the basis of the results obtained, possible separation mechanisms were considered. Hydrophilic-interaction chromatography was assumed to be the mechanism determining separation tinder normal-phase conditions, i.e. use of mobile phases containing small amounts of water. Reversed-phase chromatography occurs when water-rich mobile phases are used.
PB - Springer Heidelberg, Heidelberg
T2 - JPC-Journal of Planar Chromatography-Modern TLC
T1 - Hydrophilic-Interaction Planar Chromatography of Some Water-Soluble Co(III) Complexes on Different Adsorbents
EP - 253
IS - 4
SP - 249
VL - 22
DO - 10.1556/JPC.22.2009.4.3
UR - conv_148
ER -
@article{
author = "Radoičić, Aleksandra and Majstorović, Helena and Sabo, Tibor and Tešić, Živoslav and Milojković-Opsenica, Dušanka",
year = "2009",
abstract = "The chromatographic behavior of twelve neutral, mixed cobalt(III) complexes of the uns-cis-edda-type has been investigated in six planar chromatographic systems. Four different stationary phases unmodified silica gel, CN-silica, cellulose, and alumina - were combined with water-organic solvent (methanol or acetone) binary mobile phases. The effect of the water content of the mobile phases on retention of the complexes was investigation systematically. On the basis of the results obtained, possible separation mechanisms were considered. Hydrophilic-interaction chromatography was assumed to be the mechanism determining separation tinder normal-phase conditions, i.e. use of mobile phases containing small amounts of water. Reversed-phase chromatography occurs when water-rich mobile phases are used.",
publisher = "Springer Heidelberg, Heidelberg",
journal = "JPC-Journal of Planar Chromatography-Modern TLC",
title = "Hydrophilic-Interaction Planar Chromatography of Some Water-Soluble Co(III) Complexes on Different Adsorbents",
pages = "253-249",
number = "4",
volume = "22",
doi = "10.1556/JPC.22.2009.4.3",
url = "conv_148"
}
Radoičić, A., Majstorović, H., Sabo, T., Tešić, Ž.,& Milojković-Opsenica, D.. (2009). Hydrophilic-Interaction Planar Chromatography of Some Water-Soluble Co(III) Complexes on Different Adsorbents. in JPC-Journal of Planar Chromatography-Modern TLC
Springer Heidelberg, Heidelberg., 22(4), 249-253.
https://doi.org/10.1556/JPC.22.2009.4.3
conv_148
Radoičić A, Majstorović H, Sabo T, Tešić Ž, Milojković-Opsenica D. Hydrophilic-Interaction Planar Chromatography of Some Water-Soluble Co(III) Complexes on Different Adsorbents. in JPC-Journal of Planar Chromatography-Modern TLC. 2009;22(4):249-253.
doi:10.1556/JPC.22.2009.4.3
conv_148 .
Radoičić, Aleksandra, Majstorović, Helena, Sabo, Tibor, Tešić, Živoslav, Milojković-Opsenica, Dušanka, "Hydrophilic-Interaction Planar Chromatography of Some Water-Soluble Co(III) Complexes on Different Adsorbents" in JPC-Journal of Planar Chromatography-Modern TLC, 22, no. 4 (2009):249-253,
https://doi.org/10.1556/JPC.22.2009.4.3 .,
conv_148 .
